Emerging trends in microbial fuel cell diversification-Critical analysis

•Trends in MFC diversification was reviewed.•Microbe-electrode interactions for process intensification were reviewed.•Electrocatalyzed strategies for increasing product recovery was discussed.•Biogas upgradation/CO2 utilization to enhance product profile were discussed.•BET for waste/wastewater treatment and resource recovery was eloborated. Global need for transformation from fossil-based to bio-based economy is constantly emerging for the production of low-carbon/renewable energy/products. Microbial fuel cell (MFC) catalysed by bio-electrochemical process gained significant attention initially for its unique potential to generate energy. Diversification of MFC is an emerging trend in the context of prioritising/enhancing product output while exploring the mechanism specificity of individual processes. Bioelectrochemical treatment system (BET), microbial electrosynthesis system (MES), bioelectrochemical system (BES), electro-fermentation (EF), microbial desalination cell (MDC), microbial electrolysis cell (MEC) and electro-methanogenesis (EM) are the diversified MFC systems that are being researched actively. Owing to its broad diversification, MFC domain is increasing its potential credibility as a platform technology. Microbial catalyzed electrochemical reactions are the key which directly/indirectly are proportionally linked to electrometabolic activity of microorganisms towards final anticipated output. This review intends to holistically document the mechanisms, applications and current trends of MFC diversifications towards multi-faced applications.