The infrared predissociation spectra of water clusters
Infrared predissociation spectra of water clusters have been measured in the frequency range 3000–3800 cm−1 using a molecular beam–color center laser apparatus. The transition from a spectrum resembling that of liquid water to that of the dimer is clearly seen. Detailed theoretical analyses using no...
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Veröffentlicht in: | The Journal of chemical physics 1985-04, Vol.82 (8), p.3554-3562 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Infrared predissociation spectra of water clusters have been measured in the frequency range 3000–3800 cm−1 using a molecular beam–color center laser apparatus. The transition from a spectrum resembling that of liquid water to that of the dimer is clearly seen. Detailed theoretical analyses using normal mode theory, local mode theory, and a quantum simulation method are used to interpret the spectrum in terms of a potential surface that includes both intramolecular and intermolecular degrees of freedom. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.448935 |