Combined strategy of blending and surface modification as an effective route to prepare antifouling ultrafiltration membranes

[Display omitted] •Combined strategy of blending and surface modification was applied to construct antifouling UF membranes.•Novel nanohybrid was synthesized via TA coating on HANTs and the subsequent grafting of ZPEI.•Hybrid membranes fabricated by PSF-TA-30% and HANTs@TA-ZPEI were modified with zwitterions.•Both the membrane permeability and antifouling property achieved favorable promotion by this combined strategy. Ultrafiltration (UF) membranes blended with hydrophilic nanomaterials usually exhibit preferable overall performance including the membrane permeability and antifouling capability. However, the improvement in antifouling performance may be not outstanding due to the small amount of nanomaterial distributed near the membrane surface and the limited improvement in membrane hydrophilicity. Notably, excess addition of nanomaterials may lead to the decline in membrane permeability. In order to solve the above problem, we integrated the strategy of blending and surface modification to construct novel hybrid UF membranes. Novel nanohybrid was prepared via tannic acid (TA) coating on hydroxyapatite nanotubes (HANTs) and the subsequent grafting of zwitterionic polyethylenimine (ZPEI). The prepared nanohybrid (HANTs@TA-ZPEI) was incorporated with the polysulfone containing tertiary amine groups to fabricate hybrid membranes via the solution blending and the subsequent immersion-precipitation phase inversion process. Then the matrix was modified with zwitterions via the reaction of tertiary amine group with 1, 3-propane sultone. UF tests were conducted using the bovine serum albumin (BSA) and humic acid (HA) as the representative foulants. Results showed that both the permeability and the antifouling performance of the membranes achieved favorable promotion. Thereinto, the water flux of M-B0.4-Z membrane (pre blended with 0.4 wt% HANTs@TA-ZPEI in the casting solution and post-surface modified) exhibited 2.6 times that of the pristine membrane and the flux recovery ratio (FRR) for BSA and HA attained 93.4% and 96.1%, respectively. By the combination of blending and surface modification, both the membrane permeability and fouling resistant properties could attain remarkable promotion, which exerted the advantages of two methods and made up the deficiency of single blending method.