Tuning the configuration of the flexible metal-alkene-framework affords pure cycloisomers in solid state photodimerization

The photochemical [2+2] cycloaddition of 3,5-bis-(2-(pyridin-4-yl)vinyl)pyridine (bpvp) in the flexible Cd-based metal-alkene frameworks produced different isomeric photoproducts depending on the auxiliary and guest molecules. The bulkiness of the guest molecules influenced the conformation of the ligand, and thus the outcome of the cycloaddition reaction. The bulkiness of the guest molecules influences the conformations of the ligand and the final outcomes of the cycloaddition reaction.