Recent advances on micellar catalysis in water

Water is the universal solvent in nature to catalyze the biological transformation processes. However, owing to the immiscibility of many reagents in water, synthesis chemistry relies heavily on organic solvent. Micellar media is a green alternative to traditional petroleum feedstock derived solvents, which is recently attracting increasing research attention. The present review deals with the recent advances in micellar catalysis with an emphasis on the new “tailor-made” surfactants for various reactions. A brief overview of commercial surfactants, including anionic micelles, cationic micelles, and nonionic micelles is presented. More importantly, an attempt was made to discuss systematically the recent research progress on new surfactants by introducing structures, micellar effects and recycling process, aiming to serve as the basis for future development of surfactants. [Display omitted] •Micellar medium has heralded much interest as potentially viable alternatives to traditional petroleum feedstock derived solvents.•The recent advances of micellar catalysis assisted by commercial surfactants were reviewed.•A growing number of new“tailor-made” surfactants was designed to compete efficiently with traditional reactions in organic solvents.