Rapid solidification of Sr-contaminated soil by consecutive microwave sintering: mechanism and stability evaluation

Consecutive microwave sintering is a method proposed in this study to dispose soil contaminated by Sr during a nuclear accident by rapidly solidifying the contaminated soil. The results show that soil contaminated with 20 wt% SrSO4 and 30 wt% SrSO4 can be completely solidified by microwave sintering at 1100–1200 and 1300 ℃, respectively, for 30 min. Sr was found to be cured into slawsonite (SrAl2Si2O8) and glass structures. Moreover, soil sintered at 1300 ℃ has large cured solubility (30 wt.%), good uniformity, and excellent hardness (6.9–7.2 GPa) and chemical durability (below 1.46 × 10−5 g m−2 d−1 at 28 d). Thus, consecutive microwave sintering technology may provide a new method for treating Sr-contaminated soil in case of a nuclear accident emergency. [Display omitted] •A large-batch Sr-contaminated soil is disposed using consecutive microwave sintering for the first time.•Sr-contaminated soil is transformed into glass-ceramic solidification.•Sr in the soil can be solidified into slawsonite (SrAl2Si2O8) and a glass network simultaneously.