Single experiment measurement of residual dipolar couplings in aqueous solution using a biphasic bisperylene imide chromonic liquid crystal

Single experiment measurement of residual dipolar couplings in aqueous solution using a biphasic bisperylene imide chromonic liquid crystal

The use of the biphasic isotropic/nematic region in a bisperylene imide‐based lyotropic liquid crystal system allows the extraction of proton‐carbon 1DCH residual dipolar couplings in aqueous solution from a single F1‐coupled HSQC experiment. The method was successfully applied to the RDC‐based conf...

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Veröffentlicht in:Magnetic resonance in chemistry 2021-04, Vol.59 (4), p.408-413
Hauptverfasser: Silva, Danilo G. B., Hallwass, Fernando, Navarro‐Vázquez, Armando
Format: Artikel
Sprache:eng
Schlagworte:
Aqueous solutions
biphasic
bisperylene imide
chromonic
Conformational analysis
Couplings
Liquid crystals
RDCs
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Zusammenfassung:The use of the biphasic isotropic/nematic region in a bisperylene imide‐based lyotropic liquid crystal system allows the extraction of proton‐carbon 1DCH residual dipolar couplings in aqueous solution from a single F1‐coupled HSQC experiment. The method was successfully applied to the RDC‐based conformational analysis of sucrose.
ISSN:0749-1581
1097-458X
DOI:10.1002/mrc.5120