Identification of Barium Hydroxo-Hydroperoxostannate Precursor for Low-Temperature Formation of Perovskite Barium Stannate

Identification of Barium Hydroxo-Hydroperoxostannate Precursor for Low-Temperature Formation of Perovskite Barium Stannate

A breakthrough “superoxide colloidal solution route” for low-temperature synthesis of barium and strontium stannate perovskites and their doped analogues was recently introduced. The synthesis starts from hydrogen peroxide-rich stannate solutions and yields a so-called “crystalline superoxide molecu...

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Veröffentlicht in:Inorganic chemistry 2020-12, Vol.59 (24), p.18358-18365
Hauptverfasser: Medvedev, Alexander G, Mikhaylov, Alexey A, Shames, Alexander I, Ilyukhin, Andrey B, Churakov, Andrei V, Grishanov, Dmitry A, Mel’nik, Elena A, Tripol’skaya, Tatiana A, Lev, Ovadia, Prikhodchenko, Petr V
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Sprache:eng
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Zusammenfassung:A breakthrough “superoxide colloidal solution route” for low-temperature synthesis of barium and strontium stannate perovskites and their doped analogues was recently introduced. The synthesis starts from hydrogen peroxide-rich stannate solutions and yields a so-called “crystalline superoxide molecular cluster” that is converted by low temperature (
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.0c02993