Relationship of intrinsic viscosity of polymer solutions to molecular weight

An equation derived by Han relating intrinsic visocity to molecular weight of a polymer has been fitted to experimental data over a large range of molecular weight. Excellent fits were obtained although the Mark-Houwink equation did not fit the data over the complete molecular weight range. Han'...

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Veröffentlicht in:Polymer (Guilford) 1987-10, Vol.28 (11), p.1847-1850
1. Verfasser: McCrackin, Frank L.
Format: Artikel
Sprache:eng
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Zusammenfassung:An equation derived by Han relating intrinsic visocity to molecular weight of a polymer has been fitted to experimental data over a large range of molecular weight. Excellent fits were obtained although the Mark-Houwink equation did not fit the data over the complete molecular weight range. Han's equation may be fit to intrinsic viscosity data over a moderate range of molecular weight, and is shown to then accurately predict the intrinsic viscosities for molecular weights outside this range. A method is given to compute the two parameters of Han's equation from the Mark-Houwink parameters of a polymer in a solvent.
ISSN:0032-3861
1873-2291
DOI:10.1016/0032-3861(87)90289-8