Elucidation of a Sequential Iminium Ion Cascade Reaction Triggered by a Silica Gel-Promoted Aza-Peterson Reaction

In a recent methodological study investigating the synthesis of N-alkoxyazomethine ylides, an unexpected aminal byproduct was generated during our attempt to isolate O-benzyl-N-((trimethylsilyl)­methyl)­hydroxylamine. After a strategic investigation, silica gel was discovered to be the cause of the...

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Veröffentlicht in:	Journal of organic chemistry 2020-12, Vol.85 (23), p.15660-15666
Hauptverfasser:	Jones, Elizabeth V, Chen, Doris, Wright, Stephen W, Trujillo, John I, France, Stefan
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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