Bioinspired Hybrid Micro/Nanostructure Composited Membrane with Intensified Mass Transfer and Antifouling for High Saline Water Membrane Distillation

Membrane distillation (MD) holds great promise for high-saline solution treatment, but it is typically impeded by the trade-off between the high mass transfer and antifouling properties of the membrane. Herein, a new MD utilized membrane with bioinspired micro/nanostructure (lotus leaf and fish gill) was constructed on commercial PP membrane, which can simultaneously enhance the permeation flux and antifouling in the hypersaline MD operation. On the basis of the classic nucleation theory and hydrodynamics simulation, the nanoscale structure can intensify the interfacial nanoscale turbulent flow and hinder the crystal deposition, which works like the fish gill. In addition, the optimized nanoscale feature size renders the membrane with the heterogeneous nucleation barrier very similar to the homogeneous system, which works like the lotus leaf and hinders the induced nucleation effectively. The microscale structure as the supporting platform of nanostructure can additionally enlarge the effective evaporative surface with superior hydrophobicity and then promote the permeation transfer through the membrane. The hybrid micro/nanostructures render the fabricated membrane with excellent high-permeation flux and significantly prolonged fouling induction time, which sheds light on a new approach for the development of ideal MD utilized membrane.