Cd‐Based Metal–Organic Framework for Selective Turn‐On Fluorescent DMSO Residual Sensing
Dimethyl sulfoxide (DMSO) is a universally used solvent in various synthetic reactions, and trace amounts of DMSO residual are often seen on the surface of chemical product. It is difficult to quickly determine whether the residual DMSO is washed completely. This work reports a CdII metal–organic fr...
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| Veröffentlicht in: | Chemistry : a European journal 2021-02, Vol.27 (11), p.3753-3760 |
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| container_title | Chemistry : a European journal |
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| creator | Wang, Xiao‐Lu Tian, Jia‐Yue Guo, Xuan‐Chen Zhang, Fu‐Qiang Liang, Linfeng Zhang, Xian‐Ming |
| description | Dimethyl sulfoxide (DMSO) is a universally used solvent in various synthetic reactions, and trace amounts of DMSO residual are often seen on the surface of chemical product. It is difficult to quickly determine whether the residual DMSO is washed completely. This work reports a CdII metal–organic framework (MOF) SXU‐4 which can detect trace amounts of DMSO in various solvents. Fluorescence experiments reveal its turn‐on fluorescence effect toward DMSO with high selectivity and sensitivity, indicating that it can be used as an effective luminescent probe for rapid chemical product purity detection by testing the washing solution. Crystallographically characterized DMSO loaded SXU‐4 (DMSO@SXU‐4), in combination with computational results uncover that the enhanced DMSO–MOF conjugation through multiple DMSO–MOF supramolecule interactions and charge rearrangement are the main causes of fluorescence intensification.
Cd‐based MOF SXU‐4 can selectively and sensitively detect trace amount of DMSO in various solvents through a turn‐on based luminescence mechanism. It can be used as luminescent probe for rapid DMSO residual detection. |
| doi_str_mv | 10.1002/chem.202004111 |
| format | Article |
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Cd‐based MOF SXU‐4 can selectively and sensitively detect trace amount of DMSO in various solvents through a turn‐on based luminescence mechanism. It can be used as luminescent probe for rapid DMSO residual detection.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.202004111</identifier><identifier>PMID: 33145861</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>analytical chemistry ; Cadmium ; Chemical products ; Chemistry ; Computer applications ; Conjugation ; coordination chemistry ; Crystallography ; Dimethyl sulfoxide ; DMSO sensor ; Fluorescence ; luminescent probes ; Metal-organic frameworks ; metal–organic framework ; Selectivity ; Solvents</subject><ispartof>Chemistry : a European journal, 2021-02, Vol.27 (11), p.3753-3760</ispartof><rights>2020 Wiley‐VCH GmbH</rights><rights>2020 Wiley-VCH GmbH.</rights><rights>2021 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4101-e9b335fedefb4a587f283daaebc533e4fb42b4fd5ba5936eb6d66c33f190c7113</citedby><cites>FETCH-LOGICAL-c4101-e9b335fedefb4a587f283daaebc533e4fb42b4fd5ba5936eb6d66c33f190c7113</cites><orcidid>0000-0002-5269-0483 ; 0000-0002-8809-3402</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.202004111$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.202004111$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33145861$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Xiao‐Lu</creatorcontrib><creatorcontrib>Tian, Jia‐Yue</creatorcontrib><creatorcontrib>Guo, Xuan‐Chen</creatorcontrib><creatorcontrib>Zhang, Fu‐Qiang</creatorcontrib><creatorcontrib>Liang, Linfeng</creatorcontrib><creatorcontrib>Zhang, Xian‐Ming</creatorcontrib><title>Cd‐Based Metal–Organic Framework for Selective Turn‐On Fluorescent DMSO Residual Sensing</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Dimethyl sulfoxide (DMSO) is a universally used solvent in various synthetic reactions, and trace amounts of DMSO residual are often seen on the surface of chemical product. It is difficult to quickly determine whether the residual DMSO is washed completely. This work reports a CdII metal–organic framework (MOF) SXU‐4 which can detect trace amounts of DMSO in various solvents. Fluorescence experiments reveal its turn‐on fluorescence effect toward DMSO with high selectivity and sensitivity, indicating that it can be used as an effective luminescent probe for rapid chemical product purity detection by testing the washing solution. Crystallographically characterized DMSO loaded SXU‐4 (DMSO@SXU‐4), in combination with computational results uncover that the enhanced DMSO–MOF conjugation through multiple DMSO–MOF supramolecule interactions and charge rearrangement are the main causes of fluorescence intensification.
Cd‐based MOF SXU‐4 can selectively and sensitively detect trace amount of DMSO in various solvents through a turn‐on based luminescence mechanism. It can be used as luminescent probe for rapid DMSO residual detection.</description><subject>analytical chemistry</subject><subject>Cadmium</subject><subject>Chemical products</subject><subject>Chemistry</subject><subject>Computer applications</subject><subject>Conjugation</subject><subject>coordination chemistry</subject><subject>Crystallography</subject><subject>Dimethyl sulfoxide</subject><subject>DMSO sensor</subject><subject>Fluorescence</subject><subject>luminescent probes</subject><subject>Metal-organic frameworks</subject><subject>metal–organic framework</subject><subject>Selectivity</subject><subject>Solvents</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqF0LtOwzAUBmALgaBcVkYUiYUlxc6JnXiEQikSVSVaViLHOSmBXMBuQGw8AhJv2CfBVUuRWJgsHX3n1_FPyCGjXUZpcKofsOoGNKA0ZIxtkA7jAfMhEnyTdKgMI19wkDtk19pHSqkUANtkB4CFPBasQ-572fzj81xZzLwhzlQ5__gamamqC-31jarwrTFPXt4Yb4wl6lnxit6kNbVbGtVev2wbg1ZjPfMuhuORd4u2yFpVOl3bop7uk61clRYPVu8euetfTnoD_2Z0dd07u_F1yCjzUaYAPMcM8zRUPI7yIIZMKUw1B8DQTYM0zDOeKi5BYCoyITRAziTVEWOwR06Wuc-meWnRzpKqcGeVpaqxaW0ShDwSMQBIR4__0MfGfchd55SkMhBRHDvVXSptGmsN5smzKSpl3hNGk0XzyaL5ZN28WzhaxbZphdma_1TtgFyCt6LE93_ikt7gcvgb_g3L35If</recordid><startdate>20210219</startdate><enddate>20210219</enddate><creator>Wang, Xiao‐Lu</creator><creator>Tian, Jia‐Yue</creator><creator>Guo, Xuan‐Chen</creator><creator>Zhang, Fu‐Qiang</creator><creator>Liang, Linfeng</creator><creator>Zhang, Xian‐Ming</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5269-0483</orcidid><orcidid>https://orcid.org/0000-0002-8809-3402</orcidid></search><sort><creationdate>20210219</creationdate><title>Cd‐Based Metal–Organic Framework for Selective Turn‐On Fluorescent DMSO Residual Sensing</title><author>Wang, Xiao‐Lu ; Tian, Jia‐Yue ; Guo, Xuan‐Chen ; Zhang, Fu‐Qiang ; Liang, Linfeng ; Zhang, Xian‐Ming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4101-e9b335fedefb4a587f283daaebc533e4fb42b4fd5ba5936eb6d66c33f190c7113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>analytical chemistry</topic><topic>Cadmium</topic><topic>Chemical products</topic><topic>Chemistry</topic><topic>Computer applications</topic><topic>Conjugation</topic><topic>coordination chemistry</topic><topic>Crystallography</topic><topic>Dimethyl sulfoxide</topic><topic>DMSO sensor</topic><topic>Fluorescence</topic><topic>luminescent probes</topic><topic>Metal-organic frameworks</topic><topic>metal–organic framework</topic><topic>Selectivity</topic><topic>Solvents</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xiao‐Lu</creatorcontrib><creatorcontrib>Tian, Jia‐Yue</creatorcontrib><creatorcontrib>Guo, Xuan‐Chen</creatorcontrib><creatorcontrib>Zhang, Fu‐Qiang</creatorcontrib><creatorcontrib>Liang, Linfeng</creatorcontrib><creatorcontrib>Zhang, Xian‐Ming</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xiao‐Lu</au><au>Tian, Jia‐Yue</au><au>Guo, Xuan‐Chen</au><au>Zhang, Fu‐Qiang</au><au>Liang, Linfeng</au><au>Zhang, Xian‐Ming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cd‐Based Metal–Organic Framework for Selective Turn‐On Fluorescent DMSO Residual Sensing</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2021-02-19</date><risdate>2021</risdate><volume>27</volume><issue>11</issue><spage>3753</spage><epage>3760</epage><pages>3753-3760</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Dimethyl sulfoxide (DMSO) is a universally used solvent in various synthetic reactions, and trace amounts of DMSO residual are often seen on the surface of chemical product. It is difficult to quickly determine whether the residual DMSO is washed completely. This work reports a CdII metal–organic framework (MOF) SXU‐4 which can detect trace amounts of DMSO in various solvents. Fluorescence experiments reveal its turn‐on fluorescence effect toward DMSO with high selectivity and sensitivity, indicating that it can be used as an effective luminescent probe for rapid chemical product purity detection by testing the washing solution. Crystallographically characterized DMSO loaded SXU‐4 (DMSO@SXU‐4), in combination with computational results uncover that the enhanced DMSO–MOF conjugation through multiple DMSO–MOF supramolecule interactions and charge rearrangement are the main causes of fluorescence intensification.
Cd‐based MOF SXU‐4 can selectively and sensitively detect trace amount of DMSO in various solvents through a turn‐on based luminescence mechanism. It can be used as luminescent probe for rapid DMSO residual detection.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>33145861</pmid><doi>10.1002/chem.202004111</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-5269-0483</orcidid><orcidid>https://orcid.org/0000-0002-8809-3402</orcidid></addata></record> |
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| subjects | analytical chemistry Cadmium Chemical products Chemistry Computer applications Conjugation coordination chemistry Crystallography Dimethyl sulfoxide DMSO sensor Fluorescence luminescent probes Metal-organic frameworks metal–organic framework Selectivity Solvents |
| title | Cd‐Based Metal–Organic Framework for Selective Turn‐On Fluorescent DMSO Residual Sensing |
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