Synthesis and electron-transport properties of a stable antiaromatic NiII norcorrole with the smallest meso-substituent

Synthesis and electron-transport properties of a stable antiaromatic NiII norcorrole with the smallest meso-substituent

meso-Dimethylnorcorrole NiII complex exhibited enough stability under ambient conditions despite the distinct antiaromaticity. The small methyl substituents realized a dense and long-range π-stacking in its solid state, which resulted in the superior electron-transporting ability to previously repor...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2020-11, Vol.49 (41), p.14383-14387
Hauptverfasser: Ukai, Shusaku, Koo, Yun Hee, Fukui, Norihito, Seki, Shu, Shinokubo, Hiroshi
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography
Electron transport
Transport properties
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Zusammenfassung:meso-Dimethylnorcorrole NiII complex exhibited enough stability under ambient conditions despite the distinct antiaromaticity. The small methyl substituents realized a dense and long-range π-stacking in its solid state, which resulted in the superior electron-transporting ability to previously reported NiII norcorroles.
ISSN:1477-9226
1477-9234
DOI:10.1039/d0dt03143g