Effect of the addition of diurethane dimethacrylate on the chemical and mechanical properties of tBA-PEGDMA acrylate based shape memory polymer network

There is a great demand for the synthesis of acrylate based thermoset shape memory polymer (SMP) associated with one monomer and one crosslinker such as tert-butyl acrylate (t-BA) with poly (ethylene glycol) dimethacrylate (PEGDMA). The present work describes the synthesis of a new thermoset SMP wherein a second monomer such as diurethane dimethacrylate (DUDMA) has been added to the existing tBA + PEGDMA SMP matrix. The synthesized thermoset shape memory polymer exhibited a glass transition temperature (Tg) of 55 °C, higher Young's Modulus of 3.23 GPa, transmittance of 95% and 100% shape recovery. The SMP exhibited response to both thermal and chemical stimuli. The shape recovery rate of the SMP network is 20 s compared to 24 s observed for SMP based on tBA + PEGDMA. The obtained SMP is very transparent and possesses higher stiffness (8 MPa) and hence may be suitable for biomedical shape memory lens and orthopedic application. •Synthesis of a new biodegradable shape memory polymer by adding DUDMA.•Complete shape recovery achieved for acrylate-based shape memory polymer system.•Shape recovery rate is very less (20 s).•Young's modulus (3.23 GPa) equivalent to aircraft grade bisphenol-A diglycidyl ether epoxy resin system.•Transparent films suitable for optical applications.