Benzotetramisole catalyzed kinetic resolution of 2H-azirines

Benzotetramisole catalyzed kinetic resolution of 2H-azirines

An unprecedented benzotetramisole (BTM)-catalyzed kinetic resolution for the efficient synthesis of chiral 2H-azirines is described. This protocol provides two chiral isomers in one step with broad scope, good yield and high enantioselectivity. In addition, the optically pure 2H-azirine products hav...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-10, Vol.56 (82), p.12427-12430
Hauptverfasser: Peng, Qiupeng, Guo, Donghui, Zhang, Bei, Liu, Lala, Wang, Jian
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Crystallography
Enantiomers
Isomers
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container_title Chemical communications (Cambridge, England)
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creator Peng, Qiupeng
Guo, Donghui
Zhang, Bei
Liu, Lala
Wang, Jian
description An unprecedented benzotetramisole (BTM)-catalyzed kinetic resolution for the efficient synthesis of chiral 2H-azirines is described. This protocol provides two chiral isomers in one step with broad scope, good yield and high enantioselectivity. In addition, the optically pure 2H-azirine products have proven to be useful building blocks for further synthetic transformations.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Crystallography
Enantiomers
Isomers
title Benzotetramisole catalyzed kinetic resolution of 2H-azirines
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