Penning trap mass measurements of the deuteron and the HD+ molecular ion

The masses of the lightest atomic nuclei and the electron mass 1 are interlinked, and their values affect observables in atomic 2 , molecular 3 – 5 and neutrino physics 6 , as well as metrology. The most precise values for these fundamental parameters come from Penning trap mass spectrometry, which achieves relative mass uncertainties of the order of 10 −11 . However, redundancy checks using data from different experiments reveal considerable inconsistencies in the masses of the proton, the deuteron and the helion (the nucleus of helium-3), suggesting that the uncertainty of these values may have been underestimated. Here we present results from absolute mass measurements of the deuteron and the HD + molecular ion using 12 C as a mass reference. Our value for the deuteron mass, 2.013553212535(17) atomic mass units, has better precision than the CODATA value 7 by a factor of 2.4 and differs from it by 4.8 standard deviations. With a relative uncertainty of eight parts per trillion, this is the most precise mass value measured directly in atomic mass units. Furthermore, our measurement of the mass of the HD + molecular ion, 3.021378241561(61) atomic mass units, not only allows a rigorous consistency check of our results for the masses of the deuteron (this work) and the proton 8 , but also establishes an additional link for the masses of tritium 9 and helium-3 (ref. 10 ) to the atomic mass unit. Combined with a recent measurement of the deuteron-to-proton mass ratio 11 , the uncertainty of the reference value of the proton mass 7 can be reduced by a factor of three. Penning trap mass spectrometry is used to measure the masses of the deuteron and the HD + ion with unprecedented precision, reducing the uncertainty of the proton mass reference value.