Control of Surface Barriers in Mass Transfer to Modulate Methanol‐to‐Olefins Reaction over SAPO‐34 Zeolites

Mass transfer of guest molecules has a significant impact on the applications of nanoporous crystalline materials and particularly shape‐selective catalysis over zeolites. Control of mass transfer to alter reaction over zeolites, however, remains an open challenge. Recent studies show that, in addition to intracrystalline diffusion, surface barriers represent another transport mechanism that may dominate the overall mass transport rate in zeolites. We demonstrate that the methanol‐to‐olefins (MTO) reaction can be modulated by regulating surface permeability in SAPO‐34 zeolites with improved chemical liquid deposition and acid etching. Our results explicitly show that the reduction of surface barriers can prolong catalyst lifetime and promote light olefins selectivity, which opens a potential avenue for improving reaction performance by controlling the mass transport of guest molecules in zeolite catalysis. Surface barriers of guest molecules, which dominate the mass transport in SAPO‐34 zeolites, have been controlled to modulate performance of the methanol‐to‐olefins reaction. The reduction of surface barriers can prolong catalyst lifetime and prompt product selectivity.