A Series of Mixed-Ligand Cu(I) Complexes Comprising Diphosphine-Disulfide Ligands: Effects of Diphosphine Ligands on Luminescent Properties

Mixed-ligand Cu­(I) complexes have attracted attention as alternatives to the noble- and/or rare-metal complexes, because of their remarkable photofunctions. To develop mixed-ligand Cu­(I) complexes with rich photofunctions, an investigation of a suitable combination of ligands has captured more and more research interests. Herein, we report the first examples of emissive heteroleptic diphosphine-disulfide Cu­(I) complexes combined with diphosphine ligands. The systematic study using a series of diphosphine ligands revealed that large π-conjugated bridging moieties between the two P atoms in the diphosphine ligands result in higher light-emission performance. When the diphosphine ligand was (R)-BINAP ((R)-BINAP = (R)-(+)-2,2′-bis­(diphenylphosphino)-1,1′-binaphthyl), the Cu­(I) complex had an emission quantum yield (Φem) of 0.13 and a long emission lifetime (τem = 118 μs).