Coherent Control of Internal Conversion in Strong-Field Molecular Ionization

We demonstrate coherent control over internal conversion during strong-field molecular ionization with shaped, few-cycle laser pulses. The control is driven by interference in different neutral states, which are coupled via non-Born-Oppenheimer terms in the molecular Hamiltonian. Our measurements hi...

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Veröffentlicht in:Physical review letters 2020-07, Vol.125 (5), p.1-053202, Article 053202
Hauptverfasser: Kaufman, Brian, Rozgonyi, Tamás, Marquetand, Philipp, Weinacht, Thomas
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Sprache:eng
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Zusammenfassung:We demonstrate coherent control over internal conversion during strong-field molecular ionization with shaped, few-cycle laser pulses. The control is driven by interference in different neutral states, which are coupled via non-Born-Oppenheimer terms in the molecular Hamiltonian. Our measurements highlight the preservation of electronic coherence in nonadiabatic transitions between electronic states.
ISSN:0031-9007
1079-7114
DOI:10.1103/PhysRevLett.125.053202