Controlling photocatalytic reduction of CO2 in Ru(ii)/Re(i) dyads via linker oxidation state

Controlling photocatalytic reduction of CO2 in Ru(ii)/Re(i) dyads via linker oxidation state

Electronic communication between the linked metal centers in Ru(ii)–Re(i) dyads is tuned using the oxidation state (S and SO2) of sulfur-bridged ligands. Higher catalytic activity is seen for the SO2-bridged dyad in the photocatalytic reduction of CO2.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-01, Vol.56 (73), p.10750-10753
Hauptverfasser: Brown, Christopher M, Auvray, Thomas, DeLuca, Emile E, Ezhova, Maria B, Hanan, Garry S, Wolf, Michael O
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide
Catalytic activity
Electrochemistry
Oxidation
Photocatalysis
Valence
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Zusammenfassung:Electronic communication between the linked metal centers in Ru(ii)–Re(i) dyads is tuned using the oxidation state (S and SO2) of sulfur-bridged ligands. Higher catalytic activity is seen for the SO2-bridged dyad in the photocatalytic reduction of CO2.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc04597g