Nickel/briphos-catalyzed transamidation of unactivated tertiary amides
The transamidation of tertiary amides was achieved via nickel catalysis in combination with briphos ligands. N -Methyl- N -phenylbenzamide derivatives reacted with primary amines in the presence of NiCl 2 /briphos L4 to provide the transamidated products in moderate to good yields. Primary aromatic...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2020-08, Vol.18 (31), p.653-657 |
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| container_title | Organic & biomolecular chemistry |
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| creator | Yang, Dahyeon Shin, Taeil Kim, Hyunwoo Lee, Sunwoo |
| description | The transamidation of tertiary amides was achieved
via
nickel catalysis in combination with briphos ligands.
N
-Methyl-
N
-phenylbenzamide derivatives reacted with primary amines in the presence of NiCl
2
/briphos L4 to provide the transamidated products in moderate to good yields. Primary aromatic amines delivered higher product yields than aliphatic amines.
The transamidation of tertiary amides was achieved
via
nickel catalysis in combination with briphos ligands. |
| doi_str_mv | 10.1039/d0ob01271h |
| format | Article |
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via
nickel catalysis in combination with briphos ligands.
N
-Methyl-
N
-phenylbenzamide derivatives reacted with primary amines in the presence of NiCl
2
/briphos L4 to provide the transamidated products in moderate to good yields. Primary aromatic amines delivered higher product yields than aliphatic amines.
The transamidation of tertiary amides was achieved
via
nickel catalysis in combination with briphos ligands.</description><identifier>ISSN: 1477-0520</identifier><identifier>EISSN: 1477-0539</identifier><identifier>DOI: 10.1039/d0ob01271h</identifier><identifier>PMID: 32785322</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Aliphatic amines ; Amides ; Amines ; Catalysis ; Nickel ; Nickel chloride</subject><ispartof>Organic & biomolecular chemistry, 2020-08, Vol.18 (31), p.653-657</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-31d8ae85365fafcb3b8f04dde789827d620a38e39246ee8d1af75ccf87fde47c3</citedby><cites>FETCH-LOGICAL-c363t-31d8ae85365fafcb3b8f04dde789827d620a38e39246ee8d1af75ccf87fde47c3</cites><orcidid>0000-0001-5030-9610 ; 0000-0001-5079-3860 ; 0000-0001-5069-8687</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32785322$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yang, Dahyeon</creatorcontrib><creatorcontrib>Shin, Taeil</creatorcontrib><creatorcontrib>Kim, Hyunwoo</creatorcontrib><creatorcontrib>Lee, Sunwoo</creatorcontrib><title>Nickel/briphos-catalyzed transamidation of unactivated tertiary amides</title><title>Organic & biomolecular chemistry</title><addtitle>Org Biomol Chem</addtitle><description>The transamidation of tertiary amides was achieved
via
nickel catalysis in combination with briphos ligands.
N
-Methyl-
N
-phenylbenzamide derivatives reacted with primary amines in the presence of NiCl
2
/briphos L4 to provide the transamidated products in moderate to good yields. Primary aromatic amines delivered higher product yields than aliphatic amines.
The transamidation of tertiary amides was achieved
via
nickel catalysis in combination with briphos ligands.</description><subject>Aliphatic amines</subject><subject>Amides</subject><subject>Amines</subject><subject>Catalysis</subject><subject>Nickel</subject><subject>Nickel chloride</subject><issn>1477-0520</issn><issn>1477-0539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp90c9LwzAUB_AgipvTi3el4kWEuvxom_ao0zlhuIueS5ofLLNtapIK86-3dXOCB0958D68l3wDwCmCNwiSbCygKSDCFC33wBBFlIYwJtn-rsZwAI6cW0GIMppEh2BAME1jgvEQTJ81f5PluLC6WRoXcuZZuf6UIvCW1Y5VWjCvTR0YFbQ1415_MN93pfWa2XXQC-mOwYFipZMn23MEXqcPL5NZOF88Pk1u5yEnCfEhQSJlsludxIopXpAiVTASQtI0SzEVCYaMpJJkOEqkTAViisacq5QqISPKyQhcbeY21ry30vm80o7LsmS1NK3LcUQimEBIYUcv_9CVaW3d3a5XmNIsi0mnrjeKW-OclSpvrK66h-UI5n26-T1c3H2nO-vw-XZkW1RS7OhPnB242ADr-K77-z15I1Rnzv4z5Aszpopo</recordid><startdate>20200821</startdate><enddate>20200821</enddate><creator>Yang, Dahyeon</creator><creator>Shin, Taeil</creator><creator>Kim, Hyunwoo</creator><creator>Lee, Sunwoo</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7T7</scope><scope>7TM</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-5030-9610</orcidid><orcidid>https://orcid.org/0000-0001-5079-3860</orcidid><orcidid>https://orcid.org/0000-0001-5069-8687</orcidid></search><sort><creationdate>20200821</creationdate><title>Nickel/briphos-catalyzed transamidation of unactivated tertiary amides</title><author>Yang, Dahyeon ; Shin, Taeil ; Kim, Hyunwoo ; Lee, Sunwoo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-31d8ae85365fafcb3b8f04dde789827d620a38e39246ee8d1af75ccf87fde47c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aliphatic amines</topic><topic>Amides</topic><topic>Amines</topic><topic>Catalysis</topic><topic>Nickel</topic><topic>Nickel chloride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Dahyeon</creatorcontrib><creatorcontrib>Shin, Taeil</creatorcontrib><creatorcontrib>Kim, Hyunwoo</creatorcontrib><creatorcontrib>Lee, Sunwoo</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Nucleic Acids Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Organic & biomolecular chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Dahyeon</au><au>Shin, Taeil</au><au>Kim, Hyunwoo</au><au>Lee, Sunwoo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nickel/briphos-catalyzed transamidation of unactivated tertiary amides</atitle><jtitle>Organic & biomolecular chemistry</jtitle><addtitle>Org Biomol Chem</addtitle><date>2020-08-21</date><risdate>2020</risdate><volume>18</volume><issue>31</issue><spage>653</spage><epage>657</epage><pages>653-657</pages><issn>1477-0520</issn><eissn>1477-0539</eissn><abstract>The transamidation of tertiary amides was achieved
via
nickel catalysis in combination with briphos ligands.
N
-Methyl-
N
-phenylbenzamide derivatives reacted with primary amines in the presence of NiCl
2
/briphos L4 to provide the transamidated products in moderate to good yields. Primary aromatic amines delivered higher product yields than aliphatic amines.
The transamidation of tertiary amides was achieved
via
nickel catalysis in combination with briphos ligands.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>32785322</pmid><doi>10.1039/d0ob01271h</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-5030-9610</orcidid><orcidid>https://orcid.org/0000-0001-5079-3860</orcidid><orcidid>https://orcid.org/0000-0001-5069-8687</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-0520 |
| ispartof | Organic & biomolecular chemistry, 2020-08, Vol.18 (31), p.653-657 |
| issn | 1477-0520 1477-0539 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2434060070 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Aliphatic amines Amides Amines Catalysis Nickel Nickel chloride |
| title | Nickel/briphos-catalyzed transamidation of unactivated tertiary amides |
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