Facile synthesis of Silver@Eggshell nanocomposite: A heterogeneous catalyst for the removal of heavy metal ions, toxic dyes and microbial contaminants from water

In this work, silver nanoparticles have been synthesized with an average particle size of 35 nm, within 90s, using microwave and Sapindus mukorossi extract as a stabilizing agent. The AgNps were surface immobilized on eggshells (ES) to obtain Ag@ES, which was characterized by UV–Vis, UV-DRS, FT-IR, ICP-OES, TGA-DSC, SEM-EDX, XRD and XPS. Its applicability as an environmental catalyst was evaluated by Cr (VI) adsorption, photocatalytic degradation of methyl orange, eriochrome black-T, methylene blue, rhodamine-B as model dyes and microbial inhibition against Staphylococcus aureus, Escherichia coli and Candida albicans. The results revealed that Ag@ES exhibited maximum adsorption capacity of 93 mg/g for Cr (VI) ion and degradation efficiency of ~90–98% for removing anionic and cationic dyes. Further, it showed a minimum inhibitory concentration of 15.6, 7.8 and 31.2 μg/mL for S. aureus, E. coli and C. albicans respectively. Moreover, the Ag@ES being a heterogeneous catalyst can be regenerated and reused without significant loss in its efficiency. [Display omitted] •Stable AgNps (~35 nm) was synthesized using Sapindus mukorossi extract.•AgNps were synthesized within 90s by microwave irradiation.•AgNps were immobilized onto eggshells by a simple impregnation method.•The adsorption/photocatalytic/antimicrobial activities of Ag@ES, purifies water.•Recovered Ag@ES after usage, retained 83–98% efficiency upto 5 cycles.