Stability of lithium silicate gels

Lithium silicate gels with 15 mol% Li 2O were prepared by combining a lithium nitrate solution with partially hydrolyzed tetraethyl orthosilicate (TEOS). Using low pH and high water levels, samples were cast, gelled, and dried to form cylinders 30 mm in length and 5 mm in diameter in about a week. T...

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Veröffentlicht in:Journal of non-crystalline solids 1986-07, Vol.83 (3), p.391-399
Hauptverfasser: Schwartz, I., Anderson, P., de Lambilly, H., Klein, L.C.
Format: Artikel
Sprache:eng
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Zusammenfassung:Lithium silicate gels with 15 mol% Li 2O were prepared by combining a lithium nitrate solution with partially hydrolyzed tetraethyl orthosilicate (TEOS). Using low pH and high water levels, samples were cast, gelled, and dried to form cylinders 30 mm in length and 5 mm in diameter in about a week. The dried gels had a uniform lithium content throughout. Lithium disilicate crystals and quartz crystals appeared in samples heated above 600°C.
ISSN:0022-3093
1873-4812
DOI:10.1016/0022-3093(86)90250-4