The occurrence, characteristics, transformation and control of aromatic disinfection by-products: A review

With the development of analytical technology, more emerging disinfection by-products (DBPs) have been identified and detected. Among them, aromatic DBPs, especially heterocyclic DBPs, possess relatively high toxicity compared with regulated DBPs, which has been proved by bioassays. Thus, the occurrence of aromatic DBPs is of great concern. This article provides a comprehensive review and summary of the characteristics, occurrence, transformation pathways and control of aromatic DBPs. Aromatic DBPs are frequently detected in drinking water, wastewater and swimming pool water, among which swimming pool water illustrates highest concentration. Considering the relatively high concentration and toxicity, halophenylacetonitriles (HPANs) and halonitrophenols (HNPs) are more likely to be toxicity driver among frequently detected phenyl DBPs. Aromatic DBPs can be viewed as important intermediate products of dissolved organic matter (DOM) during chlor(am)ination. High molecular weight DOM could convert to aromatic DBPs via direct or indirect pathways, and they can further decompose into regulated aliphatic DBPs such as trihalomethanes (THMs) and haloacetic acids (HAAs) by ring opening and side chain cleavage. Even though no single DBPs control strategy is efficient to all aromatic DBPs, the decrease of overall toxicity may be achieved by several methods including absorption, solar radiation and boiling. By systematically considering aromatic DBPs and aliphatic DBPs, a better trade-off can be made to reduce health risk induced by DBPs. [Display omitted] •Halophenylacetonitriles and halonitrophenols are important potential toxicity drivers among phenyl DBPs.•In vitro and in vivo toxicological bioassays on aromatic DBPs are compared.•DOM from diverse sources forms aromatic DBPs with different characteristics.•Aromatic DBPs convert to aliphatic DBPs through ring opening or side chain cleavage.•N and halogen atoms in aliphatic DBPs originate from both aromatic DBPs and Cl2/NH2Cl.