Solution properties and chain flexibility of poly(p-tert-butylstyrene)
The dilute solution properties of anionically synthesized poly(p-tert-butylstyrene) (PtBS) were studied in tetrahydrofuran, cyclohexane 1,4-dioxane, 1-nitropropane and 2-octanol. Cyclohexane and tetrahydrofuran are good solvents for PtBS, 1,4-dioxane is of intermediate solvent power, and 1-nitroprop...
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Veröffentlicht in: | Polymer (Guilford) 1986-01, Vol.27 (1), p.129-132 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The dilute solution properties of anionically synthesized poly(p-tert-butylstyrene) (PtBS) were studied in tetrahydrofuran, cyclohexane 1,4-dioxane, 1-nitropropane and 2-octanol. Cyclohexane and tetrahydrofuran are good solvents for PtBS, 1,4-dioxane is of intermediate solvent power, and 1-nitropropane and 2-octanol are theta solvents. The unperturbed dimension results show PtBS to be a more extended chain than polystyrene. These observations are interpreted in light of rotational isomeric state (RIS) models for polystyrene and poly(p-chlorostyrene) and experimental data available for polystyrene and its substituted derivatives. |
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ISSN: | 0032-3861 1873-2291 |
DOI: | 10.1016/0032-3861(86)90367-8 |