Electron-ion recombination in gas mixtures of helium, nitrogen, and carbon dioxide

A study has been conducted to determine the electron–ion recombination rates in gas mixtures of helium, nitrogen, and carbon dioxide. Measurements were made as functions of electric field strength, gas pressure, and gas composition. In gas mixtures containing only nitrogen and carbon dioxide, the ra...

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Veröffentlicht in:J. Chem. Phys.; (United States) 1984-08, Vol.81 (3), p.1264-1270
Hauptverfasser: LITTLEWOOD, I. M, CORNELL, M. C, NYGAARD, K. J
Format: Artikel
Sprache:eng
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Zusammenfassung:A study has been conducted to determine the electron–ion recombination rates in gas mixtures of helium, nitrogen, and carbon dioxide. Measurements were made as functions of electric field strength, gas pressure, and gas composition. In gas mixtures containing only nitrogen and carbon dioxide, the rates were dependent on pressure. This dependence is interpreted as being due to the separate effects of two- and three-body recombination processes. No pressure dependence was observed for mixtures containing helium. In such mixtures, two-body recombination appears to be dominant. Moreover the addition of relatively low concentrations of helium to the discharge leads to a dramatic change in the bulk recombination rate. Two possible explanations for this observation are suggested.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.447812