A Synergistic Enhancement Strategy for Realizing Ultralong and Efficient Room‐Temperature Phosphorescence

An enhancement strategy is realized for ultralong bright room‐temperature phosphorescence (RTP), involving polymerization between phosphor monomers and acrylamide and host–guest complexation interaction between phosphors and cucurbit[6,7,8]urils (CB[6,7,8]). The non‐phosphorescent monomers exhibit 2.46 s ultralong lifetime after copolymerizing with acrylamide. The improvement is due to the rich hydrogen bond and carbonyl within the polymers which promote intersystem crossing, suppress nonradiative relaxation and shield quenchers effectively. By tuning the ratio of chromophores, a series of phosphorescent copolymers with different lifetimes and quantum yields are prepared. The complexation of macrocyclic hosts CB[6,7,8] promote the RTP of polymers by blocking aggregation‐caused quenching, and offsetting the losses of aforementioned interaction provided by polymer. Multiple lifetime‐encoding for digit and character encryption are achieved by utilizing the difference of their lifetimes. A synergistic enhancement strategy is realized for ultralong bright RTP, involving polymerization between phosphor monomers and acrylamide and host–guest complexation interaction between phosphors and cucurbit[6, 7, 8]urils (CB[6, 7, 8]). The phosphorescence lifetime and efficiency is up to 2.81 s and 76 %. Multiple lifetime‐encoding for digit and character encryption are achieved.