Flexible and Stretchable Temperature Sensors Fabricated Using Solution‐Processable Conductive Polymer Composites

Accurate monitoring of physiological temperatures is important for the diagnosis and tracking of various medical conditions. This work presents the design, fabrication, and characterization of temperature sensors using conductive polymer composites (CPCs) patterned on both flexible and stretchable substrates through both drop coating and direct ink writing (DIW). These composites were formed using a high melting point biopolymer polyhydroxybutyrate (PHB) as the matrix and the graphenic nanomaterial reduced graphene oxide (rGO) as the nanofiller (from 3 to 12 wt%), resulting in a material that exhibits a temperature‐dependent resistivity. At room temperature the composites exhibited electrical percolation behavior. Around the percolation threshold, both the carrier concentration and mobility were found to increase sharply. Sensors were fabricated by drop‐coating PHB‐rGO composites onto ink‐jet printed silver electrodes. The temperature coefficient of resistance was determined to be 0.018 /°C for pressed rGO powders and 0.008 /°C for the 3 wt% samples (the highest responsivity of all composites). Composites were found to have good selectivity to temperature with respect to pressure and moisture. Thermal mapping was demonstrated using 6 × 7 arrays of sensing elements. Stretchable devices with a meandering pattern were fabricated using DIW, demonstrating the potential for these materials in healthcare monitoring devices. Solution‐processed conductive polymer composites (CPCs) are patterned on both flexible and stretchable substrates through both drop‐coating and direct ink writing (DIW), forming sensitive temperature sensors. The composite ink comprises a high melting point biopolymer matrix (polyhydroxybutyrate [PHB]) and reduced graphene oxide (rGO) nanofiller (from 3 to 12 wt%), and exhibits a negative temperature coefficient of resistance.