Zero Liquid Discharge of Ultrahigh-Salinity Brines with Temperature Swing Solvent Extraction

Zero liquid discharge (ZLD) of hypersaline brines is technically and energetically challenging. This study demonstrates ZLD of ultrahigh-salinity brines using temperature swing solvent extraction (TSSE), a membrane-less and nonevaporative desalination technology. TSSE utilizes a low-polarity solvent...

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Veröffentlicht in:Environmental science & technology 2020-07, Vol.54 (14), p.9124-9131
Hauptverfasser: Boo, Chanhee, Billinge, Ian H, Chen, Xi, Shah, Kinnari M, Yip, Ngai Yin
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Sprache:eng
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Zusammenfassung:Zero liquid discharge (ZLD) of hypersaline brines is technically and energetically challenging. This study demonstrates ZLD of ultrahigh-salinity brines using temperature swing solvent extraction (TSSE), a membrane-less and nonevaporative desalination technology. TSSE utilizes a low-polarity solvent to extract water from brine and then releases the water as a product with the application of low-temperature heat. Complete extraction of water from a hypersaline feed, simulated by 5.0 M NaCl solution (≈292 g/L TDS), was achieved using diisopropylamine solvent. Practically all of the salt is precipitated as mineral solid waste and the product water contains
ISSN:0013-936X
1520-5851
DOI:10.1021/acs.est.0c02555