Polymer Light Emitting Diodes with Doublet Emission

Organic light-emitting radicals have developed rapidly due to their unique doublet emission and great potential in display technology. Although some organic light-emitting diodes (OLEDs) exploiting small-molecular radicals as the emitters have been reported, there is no report about the polymer-radical-based OLEDs until now. Herein, a kind of polymer radical, PS-CzTTM, is adopted as the emitter to fabricate solution-processed OLEDs. A maximum external quantum efficiency of 3.0% is achieved for a deep-red device with an emissive layer of PS-CzTTM lightly doped in 2,2′,2″-(1,3,5-benzinetriyl)-tris­(1-phenyl-1H-benzimidazole) (TPBi). Temperature-dependent time-resolved photoluminescent spectra and transient electroluminescence of radical emitters and devices are first measured. The results demonstrate that the emission channels for both thin films and devices are from the transition of doublet excitons, indicating that the unique doublet emission mechanism of radicals is maintained in PS-CzTTM films and PS-CzTTM-based OLEDs.