The force of MOFs: the potential of switchable metal-organic frameworks as solvent stimulated actuators

We evaluate experimentally the force exerted by flexible metal-organic frameworks through expansion for a representative model system, namely MIL-53(Al). The results obtained are compared with data collected from intrusion experiments while molecular simulations are performed to shed light on the re-opening of the guest-loaded structure. The critical impact of the transition stimulating medium on the magnitude of the expansion force is demonstrated. The force exerted by flexible metal-organic framework through expansion was experimentally evaluated for MIL-53(Al).