Three-body association reactions of NO+ and O2+ with N2

Three-body association reactions of NO+ and O2+ with N2

The temperature dependence of equilibrium constants for association reactions was determined using high pressure mass spectrometry during the irradiation of the cluster ions NO(+) (N2)n, where n is not greater than 5, and O2(+) (N2)n, where n is not greater than 6, by alpha particles. Attention is g...

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Veröffentlicht in:The Journal of chemical physics 1983-09, Vol.79 (5), p.2190-2199
Hauptverfasser: SPELLER, C. V, FITAIRE, M, POINTU, A. M
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Kinetics and mechanism of reactions
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Zusammenfassung:The temperature dependence of equilibrium constants for association reactions was determined using high pressure mass spectrometry during the irradiation of the cluster ions NO(+) (N2)n, where n is not greater than 5, and O2(+) (N2)n, where n is not greater than 6, by alpha particles. Attention is given to the enthalpies and entropies of clustering for n values of 1-4.
ISSN:0021-9606
1089-7690