Efficient Spin Selectivity in Self-Assembled Superhelical Conducting Polymer Microfibers

Chiral materials, natural or synthetic, have been widely studied since Pasteur’s separation of enantiomers over a century ago. The connection between electron transmission and chirality was, however, established recently where one spin was preferably selected by the chiral molecules, displaying a typical chirality-induced spin selectivity (CISS) effect. Currently, this CISS effect was mainly demonstrated in the molecular-scale devices. Herein, we explored this effect in a microscale device where an efficient spin selectivity was found in the self-assembled superhelical conducting polyaniline (PANI) microfibers. A spin-selective efficiency up to 80% (not magnetoresistance) was achieved when spins traversed the ca. 2–6 μm-long helical channels at room temperature. Importantly, the long-range ordering of chiral PANI molecules is crucial to observe this efficient spin selectivity, whereas no selective transmission was found in the “amorphous” chiral PANIs. This efficient spin selectivity was subsequently rationalized by using an extended Su–Schrieffer–Heeger model where the Rashba spin–orbit coupling was considered. We expect these results could inspire the research of organic spintronics by using molecularly ordered, self-assembled, and chiral π-conjugated materials.