Antifouling biocides as a continuous threat to the aquatic environment: Sources, temporal trends and ecological risk assessment in an impacted region of Brazil

Antifouling biocides, such as irgarol and diuron, are commonly used in antifouling paints. Recently, studies carried out in a Brazilian region of ecological concern have warned for extremely high levels of these biocides. So, this work focused on a 4-year (2015–2018) evaluation considering the occurrence, environmental fate, seasonal variations and ecological risk assessment of irgarol and diuron in water and sediment from São Marcos Bay, Brazil, which is an area of international relevance located in the Amazon region. The results showed the ubiquitous presence of antifouling biocides, as well as their wide distribution along the bay. The concentration range of irgarol was between