Reynoutria japonica, an invasive herb as a source of activated carbon for the removal of xenobiotics from water

[Display omitted] •Microwave assisted preparation of activated carbon from Reynoutria japonica.•Xenobiotics removal from water by adsorption on active carbon was assessed.•Evaluation of sorption using nonlinear regression was carried out.•Type of activating agent had significant effect on sorbent ch...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Bioresource technology 2020-08, Vol.309, p.123315-123315, Article 123315
Hauptverfasser: Koutník, Ivan, Vráblová, Martina, Bednárek, Jan
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:[Display omitted] •Microwave assisted preparation of activated carbon from Reynoutria japonica.•Xenobiotics removal from water by adsorption on active carbon was assessed.•Evaluation of sorption using nonlinear regression was carried out.•Type of activating agent had significant effect on sorbent characteristics.•H3PO4 agent gave the best active carbon for diclofenac and paracetamol sorption. Japanese knotweed (JK) is considered one of the most problematic invasive plants. Great attention was paid to research any possibilities of reducing its occurrence. This work deals with possibilities of easy transformation of JK into carbon adsorbent (AC), which is usable for sorption of diclofenac and paracetamol. Activated carbons were prepared by microwave heating using H3PO4, NaOH and sodium methanolate as the chemical agents. Characterization of AC’s was carried out using BET, ATR-FTIR, SEM, adsorption equilibrium and kinetics experiments. The pseudo-second-order model showed the best similarity criteria for all studied systems adsorbent/adsorbate. The sorption efficiency was influenced by the choice of activating agent, where the π-π interactions between the planes of the obtained adsorbent and the aromatic rings of adsorbate and the interactions between the adsorbate and AC functional groups of the surface played an important role. AC-H3PO4 exhibited highest adsorption capacity for both diclofenac (87.09 mg.g−1) and paracetamol (136.61 mg.g−1).
ISSN:0960-8524
1873-2976
DOI:10.1016/j.biortech.2020.123315