Photoredox-Assisted Gold-Catalyzed Arylative Alkoxycyclization of 1,6-Enynes
The photoredox-assisted gold-catalyzed arylative cyclization of 1,6-enynes with aryldiazonium salts gives rise to cyclization products with the opposite configuration at the alkene than that obtained by gold(I)-catalyzed alkoxycyclization. The reaction occurs under mild conditions and shows high fu...
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| Veröffentlicht in: | Organic letters 2020-04, Vol.22 (8), p.3045-3049 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The photoredox-assisted gold-catalyzed arylative cyclization of 1,6-enynes with aryldiazonium salts gives rise to cyclization products with the opposite configuration at the alkene than that obtained by gold(I)-catalyzed alkoxycyclization. The reaction occurs under mild conditions and shows high functional group tolerance. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/acs.orglett.0c00799 |