Synthesis of High Dimensionally Structured Mo–Fe Mixed Metal Oxide and Its Catalytic Activity for Selective Oxidation of Methanol

Synthesis of High Dimensionally Structured Mo–Fe Mixed Metal Oxide and Its Catalytic Activity for Selective Oxidation of Methanol

High-dimensionally structured Mo–Fe oxide (HDS-MoFeO) was synthesized through an assembly of structural units supplied from Keplerate-type polyoxometalate, {Mo72Fe30}, under an appropriate hydrothermal condition. HDS-MoFeO showed excellent catalytic activity for the selective oxidation of methanol w...

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Veröffentlicht in:Inorganic chemistry 2020-04, Vol.59 (8), p.5252-5255
Hauptverfasser: Shimoda, Kosuke, Ishikawa, Satoshi, Tashiro, Masaya, Kumaki, Masahiro, Hiyoshi, Norihito, Ueda, Wataru
Format: Artikel
Sprache:eng
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Zusammenfassung:High-dimensionally structured Mo–Fe oxide (HDS-MoFeO) was synthesized through an assembly of structural units supplied from Keplerate-type polyoxometalate, {Mo72Fe30}, under an appropriate hydrothermal condition. HDS-MoFeO showed excellent catalytic activity for the selective oxidation of methanol with slightly lower selectivity for formaldehyde than that of a conventional Mo–Fe oxide catalyst.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.9b03713