Giant Single‐Crystal Shape Transformation with Wide Thermal Hysteresis Actuated by Synergistic Motions of Molecular Cations and Anions

Manipulating the collective molecular movements to implement macroscopic mechanical response of bulk material is attractive and challenging. Here, an organic‐inorganic hybrid single crystal is synthesized, which exhibits a giant macroscopic shape transformation with a remarkable thermal hysteretic feature. The colossal anisotropic shape change, which manifests as an abrupt elongation of ca. 9 % along the crystallographic c‐axis and a concomitant contraction of ca. 9 % in a perpendicular direction, is induced by a significant reorientation of imidazolium, accompanied with a substantial configurational variation in CuBr42− complex anions. The synergistic motions of both the molecular cations and anions engender a remarkable large thermal hysteresis (>30 K) in the shape transformation of the single crystal, implying that this material may play a role in alternating memory media. Furthermore, due to the stable crystal lattice, a single crystal that demonstrates naked‐eye detectable large shape transformation was used as a thermal actuator to spontaneously control an electric circuit by temperature variation. Switch it up: A single crystal of CuII complex demonstrates an abrupt and reversible giant shape transformation with remarkable wide thermal hysteresis, as a consequence of synergetic actions of reorientation of molecular cations and geometric variation of complex anions. The giant shape deformation of single crystal can be used as a thermal actuator to spontaneously control a circuit by temperature variation.