Electrochemical generation of the naked metal anionic clusters, Sn9 − xPb4 −x (x = 0 to 9)

Electrochemical generation of the naked metal anionic clusters, Sn9 − xPb4 −x (x = 0 to 9)

An electrolytic method, using a solution of 0.1 M NaI in anhydrous ethylenediamine, produces the nine atom clusters of combinations of Sn and Pb. Nuclear magnetic resonance of 119Sn shows clusters of Sn9 -- xPb4 -- x (x = 0 to 4). After 30.4 h accumulation time. The species Sn9 -- xPb4 -- x (x = 5 t...

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Veröffentlicht in:Electrochimica acta 1981-03, Vol.26 (3), p.365-366
Hauptverfasser: Stanley Pons, B., Santure, David J., Craig Taylor, R., Rudolph, Ralph W.
Format: Artikel
Sprache:eng
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Zusammenfassung:An electrolytic method, using a solution of 0.1 M NaI in anhydrous ethylenediamine, produces the nine atom clusters of combinations of Sn and Pb. Nuclear magnetic resonance of 119Sn shows clusters of Sn9 -- xPb4 -- x (x = 0 to 4). After 30.4 h accumulation time. The species Sn9 -- xPb4 -- x (x = 5 to 9) have been identified by 207Pb nmr.7 refs.--J.J.P.
ISSN:0013-4686
DOI:10.1016/0013-4686(81)85023-2