Superhydrophilic and highly elastic monolithic sponge for efficient solar-driven radioactive wastewater treatment under one sun

[Display omitted] •The prepared monolithic sponge with superhydrophilic and highly elastic.•A rapid evaporation rate (1.60 kg m−2 h−1) and high evaporation efficiency (92 %).•Treatment with high removal efficiency for various radioactive elements.•The treatment is still effective even under radiation and acidic conditions.•The purification mechanism of radioactive wastewater have been explained. As an effective way to obtain solar energy and separate the soluble contaminants from water, solar-driven interfacial evaporation is used in desalination, wastewater treatment, electricity generation, and domestic water heating system. Herein, we demonstrate a monolithic sponge with three-dimensional porous structure as the solar-energy evaporator, which is composed of hydrophilic polymer (Konjac Glucomannan, KGM) and solar absorbent (reduced graphene oxide, rGO). Under one sun irradiation, the sponge achieves a rapid evaporation rate (1.60 kg m−2 h−1) and high interfacial water evaporation efficiency (92 %) due to its good absorption, photothermal, thermal insulation, and fast water transport properties. Meanwhile, the concentrations of radioactive elements (strontium, cesium, and uranium) in wastewater dropped from grams to micrograms after purification, even under radiation and acidic conditions. Additionally, the durability and repeatability of the sponge also have been verified. The results showed that solar-driven interfacial evaporation can effectively treat radioactive wastewater and enrich various radionuclides in a more energy-saving manner.