Synthesis, X-ray characterization and regium bonding interactions of a trichlorido(1-hexylcytosine)gold(iii) complex

Synthesis, X-ray characterization and regium bonding interactions of a trichlorido(1-hexylcytosine)gold(iii) complex

Herein we report the synthesis and X-ray characterization of a gold(iii) complex of 1-hexylcytosine via N(3). The AuCl N complexes stack on top of each other by reciprocal [AuCl] regium bonding interactions. After the first example 35 years ago, this is the second available structure of a cytosine n...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-03, Vol.56 (24), p.3524-3527
Hauptverfasser: Terrón, Angel, Buils, Jordi, Mooibroek, Tiddo J, Barceló-Oliver, Miquel, García-Raso, Angel, Fiol, Juan J, Frontera, Antonio
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
Crystallography
Gold
Synthesis
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Zusammenfassung:Herein we report the synthesis and X-ray characterization of a gold(iii) complex of 1-hexylcytosine via N(3). The AuCl N complexes stack on top of each other by reciprocal [AuCl] regium bonding interactions. After the first example 35 years ago, this is the second available structure of a cytosine nucleobase model complexed to gold(iii).
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc00505c