Concentration and distribution of polycyclic aromatic hydrocarbons in oysters from Todos os Santos Bay (Bahia, Brazil)

The aim of the present study was to evaluate the presence of polycyclic aromatic hydrocarbons (PAHs) in oysters (Crassostrea rhizophorae) collected from Todos os Santos Bay (Bahia, Brazil). The total PAH concentration was highest in Madre de Deus (36.3 to 37.8 ng g−1 in dry weight, dw), which is located near a petrochemical complex, oil refinery, and commercial port. In the Paraguaçu river estuary, PAH concentrations varied between 23.2 and 25.7 ng g−1 dw. The lowest concentrations (1.55 ng g−1 dw) were found in the Jaguaribe river estuary, which can be considered a relatively preserved area. The main source of PAHs in the study areas was observed to be pyrogenic. Values of benzo[a]pyrene toxic equivalent ranged from 0.28 to 4.20. The concentrations of PAHs in oysters from the Paraguaçu river estuary and in Madre de Deus indicate the possible lifetime risk of developing cancer in humans who feed on it. [Display omitted] •Concentrations of PAHs in oysters presented low to moderated levels.•Main source of PAHs to Todos os Santos bay is pyrogenic emissions.•Screening risk analysis indicated that some samples were not fit for human consumption.