Chiral Phosphoric Acid Catalyzed Atroposelective C−H Amination of Arenes

N‐arylcarbazole structures are important because of their prevalence in natural products and functional OLED materials. C−H amination of arenes has been widely recognized as the most efficient approach to access these structures. Conventional strategies involving transition‐metal catalysts suffer fr...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-04, Vol.59 (17), p.6775-6779
Hauptverfasser:	Xia, Wang, An, Qian‐Jin, Xiang, Shao‐Hua, Li, Shaoyu, Wang, Yong‐Bin, Tan, Bin
Format:	Artikel
Sprache:	eng
Schlagworte:	Amination Aromatic compounds atropisomerism Carbazoles Catalysts chiral phosphoric acid Cross coupling Enantiomers Exploitation heterocycles Natural products organocatalysis Oxidants Oxidizing agents Phosphoric acid Substrates
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