Total Syntheses of Lycopodium and Monoterpenoid Indole Alkaloids Based on Biosynthesis-Inspired Strategies

The merits of biogenetic considerations in the chemical syntheses of natural products have been emphasized by describing the total syntheses of Lycopodium alkaloids; lycodine, flabellidine, lycopodine, and flabelliformine, as well as monoterpenoid indole alkaloids; C-mavacurine, kopsiyunnanine K, ko...

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Veröffentlicht in:	Chemical & pharmaceutical bulletin 2020/02/01, Vol.68(2), pp.103-116
1. Verfasser:	Takayama, Hiromitsu
Format:	Artikel
Sprache:	eng
Schlagworte:	alkaloid Alkaloids Alkaloids - chemical synthesis Alkaloids - chemistry biogenetically inspired synthesis Biological Products - chemical synthesis Biological Products - chemistry biomimetic synthesis Biosynthesis Chemistry Techniques, Synthetic - methods indole alkaloid Indoles Lycopodium Lycopodium - chemistry Natural products Organic chemistry Secologanin Tryptamine Alkaloids - chemical synthesis Secologanin Tryptamine Alkaloids - chemistry total synthesis
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Beschreibung
Zusammenfassung:	The merits of biogenetic considerations in the chemical syntheses of natural products have been emphasized by describing the total syntheses of Lycopodium alkaloids; lycodine, flabellidine, lycopodine, and flabelliformine, as well as monoterpenoid indole alkaloids; C-mavacurine, kopsiyunnanine K, koumine, and 11-methoxy-19R-hydroxygelselegine.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.c19-00872