Combining unsaturated metal sites and narrow pores within a Co(ii)-based MOF towards CO2 separation and transformation

Combining unsaturated metal sites and narrow pores within a Co(ii)-based MOF towards CO2 separation and transformation

A Co(ii)-based MOF, {[Co3(L)2(bpb)(DMA)(H2O)]·Solvents}n (RH-1), with a unique interpenetrated framework has been solvothermally prepared. Because of its unsaturated metal sites and narrow pores inside the framework, RH-1 demonstrated excellent selective CO2 adsorption over N2 and CH4 and good perfo...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2020-02, Vol.49 (7), p.2058-2062
Hauptverfasser: Zhang, Xiuling, Ran-Hui, Zhang, Hu, Hui, Geng, Longlong, Yong-Zheng, Zhang, Gao, Jun, Da-Shuai, Zhang, Yao-Qiang, Jin, Sheng, Jianmin
Format: Artikel
Sprache:eng
Schlagworte:
Adsorption
Carbon dioxide
Carbonates
Catalytic converters
Crystallography
Metal-organic frameworks
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Zusammenfassung:A Co(ii)-based MOF, {[Co3(L)2(bpb)(DMA)(H2O)]·Solvents}n (RH-1), with a unique interpenetrated framework has been solvothermally prepared. Because of its unsaturated metal sites and narrow pores inside the framework, RH-1 demonstrated excellent selective CO2 adsorption over N2 and CH4 and good performance in catalytic CO2 conversion to cyclic carbonates under mild conditions.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt04736k