Synergic Exfoliation of Graphene with Organic Molecules and Inorganic Ions for the Electrochemical Production of Flexible Electrodes

A facile and efficient method based on electrochemistry for the production of graphene‐based materials for electronics is demonstrated. Uncharged acetonitrile molecules are intercalated in graphite by electrochemical treatment, owing to the synergic action of perchlorate ions dissolved in acetonitrile. Then, acetonitrile molecules are decomposed with microwave irradiation, which causes gas production and rapid graphite exfoliation, with an increase in the graphite volume of up to 600 %. Upon further processing and purification, highly dispersible nanosheets are obtained that can be processed into thin layers by roll‐to‐roll transfer or into thicker electrodes with excellent capacitance stability upon extensive charging/discharging cycles. The good exfoliation yield (>50 % of monolayers), minimal oxidation damage and good electrochemical stability of the nanosheets obtained were confirmed by scanning force and electron microscopy, as well as Raman spectroscopy and galvanostatic analyses. Sneak attack! Inorganic ions are used as Trojan horses to favor the intercalation of organic acetonitrile molecules into graphite. These molecules act as nanoscopic foaming agents and decompose with microwave irradiation to generate a pressure surge within graphite to exfoliate it (see picture). The process yields highly soluble, monoatomic, large sheets.