Modular synthesis of (C-10 to C-13)-substituted-9,14-diaryl-9,14-dihydrodibenzo[a,c]phenazines via a subsequent Buchwald-Hartwig amination and C-H amination strategy

Herein, we report a modular synthetic approach of (C-10 to C-13)-substituted 9,14-diaryl-9,14-dihydrodibenzo[a,c]phenazine derivatives. This synthetic route enables the aromatic substitution in a predictable and programmed manner to obtain products in synthetically useful isolated yield.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-02, Vol.56 (15), p.2260-2263
Hauptverfasser: Li, Xiaobin, Zhang, Chengxi, Wang, Chenchen, Ye, Wenqiang, Zhang, Qian, Zhang, Zhiyun, Su, Jianhua, Chen, Yifeng, Tian, He
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Sprache:eng
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Zusammenfassung:Herein, we report a modular synthetic approach of (C-10 to C-13)-substituted 9,14-diaryl-9,14-dihydrodibenzo[a,c]phenazine derivatives. This synthetic route enables the aromatic substitution in a predictable and programmed manner to obtain products in synthetically useful isolated yield.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc09997b