Molecular Engineering of Isomeric Benzofurocarbazole Donors for Photophysical Management of Thermally Activated Delayed Fluorescence Emitters

Benzofurocarbazole moieties are commonly used donor structures in the design of thermally activated delayed fluorescence (TADF) emitters. However, only 5 H‐benzofuro[3,2‐c]carbazole (34BFCz) has been reported and, to the best of our knowledge, no other benzofurocarbazole derivatives have been covered in the literature. In the present study, two further benzofurocarbazole moieties, 12 H‐benzofuro[3,2‐a]carbazole (12BFCz) and 7 H‐benzofuro[2,3‐b]carbazole (23BFCz), have been synthesized to investigate the effect of the donor structure on the photophysics and device parameters of TADF emitters. Two benzofurocarbazole‐derived TADF emitters, 12‐(2‐(4,6‐diphenyl‐1,3,5‐triazin‐2‐yl)phenyl)‐12 H‐benzofuro[3,2‐a]carbazole (o12BFCzTrz) and 7‐(2‐(4,6‐diphenyl‐1,3,5‐triazin‐2‐yl)phenyl)‐7 H‐benzofuro[2,3‐b]carbazole (o23BFCzTrz), have been compared with 5‐(2‐(4,6‐diphenyl‐1,3,5‐triazin‐2‐yl)phenyl)‐5 H‐benzofuro[3,2‐c]carbazole (oBFCzTrz). The benzofurocarbazole donor structure governs the TADF characteristics, such as charge‐transfer property and emission color. The 12BFCz donor has proved to be effective in blue‐shifting the emission color, and 34BFCz has proven useful for improving the external quantum efficiency (EQE). The 12BFCz‐derived o12BFCzTrz showed blue‐shifted color coordinates of (0.159, 0.288), compared to (0.178, 0388) for o23BFCzTrz and (0.169, 0.341) for oBFCzTrz. The 34BFCz‐derived oBFCzTrz exhibited an EQE of 22.9 %, compared to 19.2 % for o12BFCzTrz and 21.1 % for o23BFCzTrz. Tuning delayed fluorescence: The effects of isomeric benzofurocarbazole donor structures on the photophysical properties of thermally activated delayed fluorescence (TADF) emitters have been investigated.