Porous composite architecture bestows Fe-based glassy alloy with high and ultra-durable degradation activity in decomposing azo dye

[Display omitted] •Peculiar porous architecture with Ni supported Fe-Si-B glass is constructed.•Over 1000 % improvement in kinetic rate is achieved in degradation tests.•Structural electrocatalysis accelerates the degradation process.•The composite architecture bestows the material with high self-cleaning ability.•Superb durability of over 100 degradation cycles is revealed. Since the treatment of wastewater containing azo dye presents problems worldwide, it is important to seek effective materials and technology for the purification of wastewater containing azo dye. Fe-based metallic glasses have been identified as promising materials for the decomposition of dyeing wastewater due to their high chemical activity resulting from their amorphous structure. It is imperative to further improve their degradation performance, and especially their durability, for potential application in wastewater purification. Here, composite structures constructed of porous Ni and amorphous Fe78Si9B13 powder with markedly enhanced degradation performance in Orange II solution were obtained by utilizing a magnet. Due to the favorable effects of structural electrocatalysis and high dispersity of the distinctive porous architecture in addition to its self-cleaning properties, the solid-liquid interface exhibited strong, continuous electrical and mass transport, and a compelling improvement in degradation performance was achieved. Based on degradation tests and spectrum analysis, the kinetic rate was improved over 11-fold. Moreover, ultra-high durability over 100 cycles was revealed in cycling tests. The results indicate that wastewater degradation performance can be greatly enhanced by properly combining Fe-based metallic glasses with porous material.