New frontiers for solid-state NMR across the periodic table: a snapshot of modern techniques and instrumentation

Selected highlights of the recent literature on solid-state NMR of some of the lesser studied nuclei are provided. The roles of ultrahigh magnetic fields, radiofrequency pulse sequences, dynamic nuclear polarization, isotopic enrichment, and nuclear quadrupole resonance in opening up the periodic table to in-depth study are discussed. Advances in solid-state NMR spectroscopy which continue to open up the periodic table to further exploration are surveyed.